Pressure Swing Adsorption for CO2 Removal from Calcium Carbide and Yellow Phosphorus Off-Gases
Release Date:
2010-12-06
Source:
Due to the high propensity of elemental phosphorus to ignite spontaneously and its severe corrosive effects on steel upon combustion, yellow-phosphorus tail gas cannot be recovered at all. The conventional process involves high-altitude flaring followed by direct venting, resulting in substantial resource waste and severe environmental pollution.
The company employs a specialized process and its proprietary, high-performance adsorbent to purify yellow-phosphorus tail gas for the production of high-value-added products such as sodium formate, formic acid, oxalic acid, and methanol. Following purification, the hydrogen sulfide content in the yellow-phosphorus tail gas is <10 mg/m 3 , total phosphorus content <10 mg/m 3 , arsenic content <0.5 mg/m 3 , hydrogen fluoride content <5 mg/m 3 , to meet the feed gas requirements for the production of one-carbon chemical products.
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